You will need a Gnomon (an object that is vertical and casts a shadow at solar noon). Measure the length of the shadow cast by the Gnomon at solar noon (you can find the time of solar noon at TimeandDate.com). You also need to measure the height of the Gnomon. Enter the length of the shadow and the height of the Gnomon (in cm) below and press "calculate the Sun's Altitude" to calculate the altitude of the Sun (the angle up from the horizon to the Sun).
Click here to see the details of the calculations done by the webpage